Articles, systems, and methods for forging alloys

ABSTRACT

A system and method of processing an alloy ingot or other alloy workpiece to reduce thermal cracking and reduce friction between the workpiece and the forging die may generally comprise positioning a multi-layer pad between the workpiece and the forging die. An article for processing an alloy ingot or other alloy workpiece to reduce thermal cracking also is disclosed. The present disclosure also is directed to an alloy workpieces processed according to the methods described herein, and to articles of manufacture including or made from alloy workpieces made according to these methods.

CROSS-REFERENCE TO RELATED APPLICATIONS

This patent application is a continuation application claiming priorityunder 35 U.S.C. §120 to co-pending U.S. patent application Ser. No.13/833,043, filed on Mar. 15, 2013, which patent application is herebyincorporated herein by reference in its entirety.

TECHNICAL FIELD

The present disclosure is directed to alloy ingots and other alloyworkpieces. More particularly, the present disclosure is directed toarticles, systems, and methods for processing alloy ingots and otheralloy workpieces.

BACKGROUND

“Forging” refers to the working and/or shaping of a solid-state materialby plastic deformation. Forging is distinguishable from the otherprimary classifications of solid-state material forming operations,i.e., machining (shaping of a workpiece by cutting, grinding, orotherwise removing material from the workpiece) and casting (moldingliquid material that solidifies to retain the shape of a mold).“Forgeability” is the relative capacity of a material to plasticallydeform without failure. Forgeability depends on a number of factorsincluding, for example, forging conditions (e.g., workpiece temperature,die temperature, and deformation rate) and material characteristics(e.g., composition, microstructure, and surface structure). Anotherfactor that affects the forgeability of a given workpiece is thetribology of the interacting die surfaces and workpiece surfaces. Theinteraction between die surfaces and workpiece surfaces in a forgingoperation involves heat transfer, friction, and wear. As such, thermalinsulation and/or lubrication between a workpiece and forging dies caninfluence forgeability.

Various alloys may be characterized as being “crack sensitive”. Ingotsand other workpieces composed of crack sensitive alloys may form cracksalong their surfaces and/or edges during forging operations orinternally if material at the surface and interior move at differentrates. Forming articles from crack sensitive alloys may be problematicbecause, for example, cracks formed during forging or other hot workingoperations may need to be removed from the worked article, whichincreases production time and expense, while reducing yield.

It is known in the art to decrease friction during forging operations byusing lubricants. Inadequate or inconsistent forging lubrication canresult in non-uniform plastic deformation of the workpiece, which isgenerally undesirable. For example, non-uniform plastic deformation canresult in “barreling” of the workpiece and/or the formation of voids inthe workpiece during forging operations. However, prior forginglubricants may have various deficiencies that result in a sub-standardforged article.

Given the drawbacks of current forging techniques, it would beadvantageous to provide a more efficient and/or more cost-effectivemethod of forging alloys, especially crack sensitive alloys.Additionally, it would be advantageous to decrease the friction betweendies and workpieces during forging operations. More generally, it wouldbe advantageous to provide an improved method for forging alloy ingotsand other alloy workpieces.

SUMMARY

According to certain non-limiting embodiments, articles, systems, andmethods for processing alloy ingots and other alloy workpieces aredescribed.

Various non-limiting embodiments according to the present disclosure aredirected to a system for forging a workpiece. The system can comprise adie, an alloy workpiece, and a pad positioned intermediate at least aportion of the die and the alloy workpiece. The pad can comprise aplurality of layers, including a first layer having a first thermalresistance and a first coefficient of friction, and a second layerhaving a second thermal resistance and a second coefficient of friction.The first thermal resistance can be greater than the second thermalresistance, and the first coefficient of friction can be greater thanthe second coefficient of friction. In various non-limiting embodiments,first layer comprises KOAWOOL and the second layer comprises fiberglass.

Additional non-limiting embodiments according to the present disclosureare directed to a multi-layer pad for use during a forging operation,wherein the multi-layer pad comprises a first lubricative layer, asecond lubricative layer, and a first insulative layer positionedintermediate the first and second lubricative layers. The firstlubricative layer can further comprise a workpiece-contacting surface,and the second lubricative layer can further comprise a die-contactingsurface. At least one of the first and second lubricative layers cancomprise fiberglass, and the first insulative layer can comprise ceramicfibers. The coefficient of friction of the first and second lubricativelayers can be less than the coefficient of friction of the firstinsulative layer and/or the thermal conductivity of the first insulativelayer can be less than the thermal conductivity of the first and secondlubricative layers. In various non-limiting embodiments, the multi-layerpad can comprise a fastener for fastening at least the first and secondlubricative layers relative to each other. Further, in variousnon-limiting embodiments the first and second lubricative layers canform a sleeve into which the insulative layer is disposed.

Still more non-limiting embodiments according to the present disclosureare directed to a method for hot working a workpiece, the methodcomprising: heating an alloy workpiece to a temperature above theambient temperature; positioning a multi-layer pad between the alloyworkpiece and a die, wherein the multi-layer pad comprises a lubricationlayer and a thermal resistance layer; and hot working the alloyworkpiece. Hot working the alloy workpiece can comprise applying a forcewith the die to the alloy workpiece to plastically deform the alloyworkpiece. Applying a force with the die to the alloy workpiece toplastically deform the alloy workpiece can comprise upset forging thealloy workpiece. The method can further comprise positioning a pluralityof multi-layer pads between the alloy workpiece and at least one die,pre-forming the alloy workpiece, and/or fabricating an article from thehot worked alloy workpiece. Exposing the workpiece to temperatures abovethe ambient temperature can comprise heating the alloy workpiece to atemperature above the recrystallization temperature of the alloy andbelow the melting point temperature of the alloy

Further non-limiting embodiments according to the present disclosure aredirected to alloy workpieces made or processed according to any of themethods of the present disclosure.

Yet further non-limiting embodiments according to the present disclosureare directed to articles of manufacture made from or including alloyworkpieces made or processed according to any of the methods of thepresent disclosure. Such articles of manufacture include, for example,jet engine components, land based turbine components, valves, enginecomponents, shafts, and fasteners.

DESCRIPTION OF THE DRAWING FIGURES

The various non-limiting embodiments described herein may be betterunderstood by considering the following description in conjunction withthe accompanying drawing figures, in which:

FIGS. 1A-1C are cross-sectional schematic diagrams illustrating animpression die upset forging method for forming a headed fastener;

FIG. 2A is an elevational view of a headed fastener formed by theimpression die upset forging method depicted in FIGS. 1A-1C;

FIG. 2B is a detail view of the head of the headed fastener of FIG. 2A;

FIG. 3A is a cross-sectional schematic diagram illustrating an open dieupset forging system operating under frictionless conditions;

FIG. 3B is a cross-sectional schematic diagram illustrating an open dieupset forging system operating under high friction conditions;

FIGS. 4A and 4B are cross-sectional schematic diagrams illustrating anopen die upset forging operation with a multi-layer pad positionedbetween the open die and the workpiece, according to variousnon-limiting embodiments of the present disclosure;

FIG. 5 is a schematic diagram illustrating an impression die upsetforging system with a multi-layer pad positioned between the impressiondie and the workpiece, according to various non-limiting embodiments ofthe present disclosure;

FIG. 6A is an elevational view of a headed fastener formed by theimpression die upset forging system depicted in FIG. 5, according tovarious non-limiting embodiments of the present disclosure;

FIG. 6B is a detail view of the head of the headed fastener of FIG. 6A,according to various non-limiting embodiments of the present disclosure;

FIG. 7 is a perspective view of a multi-layer pad for use in forgingoperations, according to various non-limiting embodiments of the presentdisclosure;

FIG. 8 is an elevational view of the multi-layer pad of FIG. 7,according to various non-limiting embodiments of the present disclosure;

FIG. 9 is a cross-sectional elevational view of a multi-layer pad foruse in forging operations, according to various non-limiting embodimentsof the present disclosure;

FIG. 10 is a plan view of the multi-layer pad of FIG. 9, according tovarious non-limiting embodiments of the present disclosure;

FIG. 11 is a plan view of a multi-layer pad for use in forgingoperations, depicting the multi-layer pad in a partially-assembledconfiguration, according to various non-limiting embodiments of thepresent disclosure; and

FIG. 12 is a plan view of the multi-layer pad of FIG. 11, depicting themulti-layer pad in an assembled configuration, according to variousnon-limiting embodiments of the present disclosure.

DESCRIPTION OF CERTAIN NON-LIMITING EMBODIMENT

It is to be understood that various descriptions of the disclosedembodiments have been simplified to illustrate only those features,aspects, characteristics, and the like that are relevant to a clearunderstanding of the disclosed embodiments, while eliminating, forpurposes of clarity, other features, aspects, characteristics, and thelike. Persons having ordinary skill in the art, upon considering thepresent description of the disclosed embodiments, will recognize thatother features, aspects, characteristics, and the like may be desirablein a particular implementation or application of the disclosedembodiments. However, because such other features, aspects,characteristics, and the like may be readily ascertained and implementedby persons having ordinary skill in the art upon considering the presentdescription of the disclosed embodiments, and are, therefore, notnecessary for a complete understanding of the disclosed embodiments, adescription of such features, aspects, characteristics, and the like isnot provided herein. As such, it is to be understood that thedescription set forth herein is merely exemplary and illustrative of thedisclosed embodiments and is not intended to limit the scope of theinvention as defined solely by the claims.

In the present disclosure, other than where otherwise indicated, allnumbers expressing quantities or characteristics are to be understood asbeing prefaced and modified in all instances by the term “about.”Accordingly, unless indicated to the contrary, any numerical parametersset forth in the following description may vary depending on the desiredproperties one seeks to obtain in the embodiments according to thepresent disclosure. For example, the term “about” can refer to anacceptable degree of error for the quantity measured, given the natureor precision of the measurement. Typical exemplary degrees of error maybe within 20%, within 10%, or within 5% of a given value or range ofvalues. At the very least, and not as an attempt to limit theapplication of the doctrine of equivalents to the scope of the claims,each numerical parameter described in the present description should atleast be construed in light of the number of reported significant digitsand by applying ordinary rounding techniques.

Also, any numerical range recited herein is intended to include allsub-ranges subsumed therein. For example, a range of “1 to 10” isintended to include all sub-ranges between (and including) the recitedminimum value of 1 and the recited maximum value of 10, that is, havinga minimum value equal to or greater than 1 and a maximum value equal toor less than 10. Any maximum numerical limitation recited herein isintended to include all lower numerical limitations subsumed therein,and any minimum numerical limitation recited herein is intended toinclude all higher numerical limitations subsumed therein. Accordingly,Applicants reserve the right to amend the present disclosure, includingthe claims, to expressly recite any sub-range subsumed within the rangesexpressly recited herein. All such ranges are intended to be inherentlydisclosed herein such that amending to expressly recite any suchsub-ranges would comply with the requirements of 35 U.S.C. §112, firstparagraph, and 35 U.S.C. §132(a).

The grammatical articles “one”, “a”, “an”, and “the”, as used herein,are intended to include “at least one” or “one or more”, unlessotherwise indicated. Thus, the articles are used herein to refer to oneor more than one (i.e., to at least one) of the grammatical objects ofthe article. By way of example, “a component” means one or morecomponents, and thus, possibly, more than one component is contemplatedand may be employed or used in an implementation of the describedembodiments.

Any patent, publication, or other disclosure material that is said to beincorporated by reference herein, is incorporated herein in its entiretyunless otherwise indicated, but only to the extent that the incorporatedmaterial does not conflict with existing definitions, statements, orother disclosure material expressly set forth in this disclosure. Assuch, and to the extent necessary, the express disclosure as set forthherein supersedes any conflicting material incorporated by referenceherein. Any material, or portion thereof, that is said to beincorporated by reference herein, but which conflicts with existingdefinitions, statements, or other disclosure material set forth hereinis only incorporated to the extent that no conflict arises between thatincorporated material and the existing disclosure material. Applicantreserves the right to amend the present disclosure to expressly reciteany subject matter, or portion thereof, incorporated by referenceherein.

The present disclosure includes descriptions of various non-limitingembodiments. It is to be understood that all embodiments describedherein are exemplary, illustrative, and non-limiting. Thus, theinvention is not limited by the description of the various exemplary,illustrative, and non-limiting embodiments. Rather, the invention isdefined solely by the claims, which may be amended to recite anyfeatures expressly or inherently described in or otherwise expressly orinherently supported by the present disclosure. Therefore, any suchamendments would comply with the requirements of 35 U.S.C. §112, firstparagraph, and 35 U.S.C. §132(a).

The various non-limiting embodiments disclosed and described herein cancomprise, consist of, or consist essentially of, the features, aspects,characteristics, limitations, and the like, as variously describedherein. The various non-limiting embodiments disclosed and describedherein can also comprise additional or optional features, aspects,characteristics, limitations, and the like, that are known in the art orthat may otherwise be included in various non-limiting embodiments asimplemented in practice.

As used herein, the term “hot working” refers to the application offorce to a solid-state workpiece at any temperature greater than ambienttemperature, wherein the applied force plastically deforms theworkpiece.

During hot working operations, such as, for example, forging operationsand extrusion operations, a force may be applied to an alloy ingot orother alloy workpiece at a temperature greater than ambient temperature,such as above the recrystallization temperature of the workpiece, toplastically deform the workpiece. The temperature of an alloy ingot orother alloy workpiece undergoing the hot working operation may begreater than the temperature of the dies or other structures used tomechanically apply force to the surfaces of the workpiece. The alloyingot or other alloy workpiece may form temperature gradients due tocooling of its surface by heat loss to ambient air and the thermalgradient off-set between its surfaces and the contacting dies or otherstructures. The resulting thermal gradient off-set between the alloyworkpiece surfaces and the interior portions of the alloy workpiece maycontribute to cracking of the ingot along its surfaces and/or edgesduring hot working. Surface cracking is especially problematic insituations in which the alloy ingots or other alloy workpieces areformed from crack sensitive alloys.

Various alloys may be characterized as crack sensitive. Crack sensitivealloys tend to form cracks during working operations. Crack sensitivealloy ingots, for example, may form cracks during hot working operationsused to produce alloy articles from the crack sensitive alloy ingots.For example, alloy billets may be formed from alloy ingots using forgeconversion. Other alloy articles may be formed from alloy billets oralloy ingots using extrusion or other working operations. The productionyield of alloy articles (e.g., alloy billets) formed from cracksensitive alloy ingots using hot working operations may be low becauseof the incidence of surface cracking of the alloy ingots during the hotworking (e.g., during forging or extrusion). The production yields maybe reduced by a need to grind off or otherwise remove the surface cracksfrom a worked ingot.

According to various non-limiting embodiments, various nickel basealloys, iron base alloys, nickel-iron base alloys, titanium base alloys,titanium-nickel base alloys, cobalt base alloys, and superalloys, suchas nickel base superalloys, may be crack sensitive, especially duringhot working operations. An alloy ingot or other alloy workpiece may beformed from such crack sensitive alloys and superalloys. For example, acrack sensitive alloy workpiece may be formed from alloys or superalloysselected from, but not limited to, Alloy 718 (UNS No. N07718), Alloy 720(UNS No. N07720), Rene 41 alloy (UNS No. N07041), Rene 65 alloy, Rene 88alloy, Waspaloy® alloy (UNS No. N07001), and Inconel® 100 alloy.

FIGS. 1A-1C depict a hot working upset forging process wherein afastener is headed. In various non-limiting embodiments, an impressiondie 10 and a punch 12 can be used to upset forge a portion of aworkpiece, such as a wire or metal rod 20, for example. The wire 20 canbe heated to a temperature above the ambient temperature, for example,while the die 10 and/or the punch 12 remains at and/or below the ambienttemperature. Referring primarily to FIG. 1A, the wire 20 can be heldwithin the die 10, and can extend into an opening or cavity 16 in thedie 10. In various non-limiting embodiments, the punch 12 can be movedin a direction “X” toward the die 10. For example, the punch 12 can moveinto the opening 16 in the die 10 and contact and exert a force on thewire 20. In various non-limiting embodiments, the force exerted on thewire 20 by the punch 12 can deform the wire 20 to form a head 22 (FIG.1B). In other words, the head 22 can be formed between a contactingsurface of the punch 12 and a contacting surface of the die 10.Referring primarily to FIG. 1C, the punch 12 can be removed from theopening 16 and the wire 20 can be advanced through the die 10. Invarious non-limiting embodiments, a blade 14 can cut the wire 20 suchthat the formed fastener 24 (shown in FIG. 2A) is released from theforging die 10.

In various non-limiting embodiments, the wire 20 can be comprised of acrack sensitive alloy. For example, the wire 20 can be made of a cracksensitive alloy selected from Alloy 718, Alloy 720, Rene 41 alloy, Rene65 alloy, Rene 88 alloy, Waspaloy® alloy, and Inconel® 100 alloy. Insuch embodiments, the thermal gradient off-set between the wire 20 andthe surfaces of the die 10 and/or the punch 12 that contact the wire 20can result in cracking along the surfaces and/or edges of the formedfastener 24. Referring to FIGS. 2A and 2B, an exemplary fastener 24produced by the upset forging hot working process depicted in FIGS.1A-1C can comprise various cracks along the forged surfaces thereof. Forexample, referring primarily to FIG. 2B, the surface 28 of the fastenerhead 26 can comprise various cracks resulting from the thermal gradientoff-set during forging of the head 26. In certain non-limitingembodiments, the fastener 24 may require subsequent machining to removecracked material from the surface 28 thereof.

One technique used to reduce crack formation on the surfaces and edgesof alloy ingots or other alloy workpieces during hot working is to placethe alloy ingots into an alloy can before hot working. With cylindricalworkpieces, for example, the inside diameter of the alloy can isslightly larger than the outside diameter of the alloy workpiece,thereby allowing the insertion of the workpiece into the can. The canloosely surrounds the workpiece, providing an air gap between the can'sinner surfaces and the workpiece. During hot working operations, thedies contact the external can, and the can thermally insulates the alloyworkpiece by action of the air gaps and also by directly inhibiting thealloy workpiece from radiating heat to the environment. In this manner,the can may thermally insulate and mechanically protect surfaces of theworkpiece, which may reduce the incidence of workpiece surface crackingduring working.

An alloy workpiece canning operation may result in variousdisadvantages. For example, mechanical contact between dies and thealloy can's outer surfaces may break apart the can. In one specificcase, during repeated upset forging of a canned workpiece, the alloy maybreak apart between upset forging operations. In such case, the alloyworkpiece may need to be re-canned between upset forging operations,which increases process complexity and expense. In another specificcase, during upset-and-draw forging of a canned workpiece, the alloy canmay break apart during the draw operation. In such case, the alloyworkpiece may need to be re-canned between each upset-and-draw cycle ofa multiple upset-and-draw forging operation, which increases processcomplexity and expense. Further, the alloy can may impair an operatorfrom visually monitoring the surface of a canned alloy workpiece forcracks and other work-induced defects.

The following co-owned U.S. patents and patent applications, related tovarious devices and/or methods for reducing the incidence of surfacecracking of an alloy ingot or other alloy workpiece during hot working,are hereby incorporated by reference herein in their respectiveentireties:

U.S. Pat. No. 8,230,899, entitled “SYSTEMS AND METHODS FOR FORMING ANDPROCESSING ALLOY INGOTS”;

U.S. patent application Ser. No. 12/700,963, entitled “SYSTEMS ANDMETHODS FOR PROCESSING ALLOY INGOTS”, published as U.S. PatentApplication Publication No. 2011/0195270;

U.S. patent application Ser. No. 13/007,692, entitled “HOT WORKABILITYOF METAL ALLOYS VIA SURFACE COATING”, published as U.S. PatentApplication Publication No. 2012/0183708; and

U.S. patent application Ser. No. 13/533,142, entitled “SYSTEMS ANDMETHODS FOR FORMING AND PROCESSING ALLOY INGOTS”, published as U.S.Patent Application Publication No. 2012/0279678.

In forging operations, the interface friction between workpiece surfacesand die surfaces may be quantitatively expressed as the frictional shearstress. The frictional shear stress (T) may be expressed as a functionof the solid flow stress of the deforming material (σ) and the shearfriction factor (m) by the following equation:

$T = {\frac{m}{\sqrt{3}}{\sigma.}}$

The value of the shear friction factor provides a quantitative measureof lubricity for a forging system. For example, the shear frictionfactor may range from 0.6 to 1.0 when forging titanium alloy workpieceswithout lubricants, whereas the shear friction factor may range from 0.1to 0.3 when hot forging titanium alloy workpieces with certain moltenlubricants. Lubricity, quantified as the shear friction factor (m) of asystem, may be measured using a ring compression test in which a flatring-shaped specimen is compressed to a predetermined reduction inheight. Ring compression testing is known to those having ordinary skilland is generally described, for example, in Altan et al., Metal Forming:Fundamentals and Applications, Ch. 6. “Friction in Metal Forming”, ASM:1993, which is incorporated by reference herein.

Inadequate forging lubrication, characterized, for example, by arelatively high value of the shear friction factor for a forgingoperation, may have a number of adverse effects. In forging, thesolid-state flow of material is caused by the force transmitted from thedies to the plastically deforming workpiece. The frictional conditionsat the die/workpiece interface influence metal flow, formation ofsurface and internal stresses within the workpiece, stresses acting onthe dies, and pressing load and energy requirements. FIGS. 3A and 3Billustrate certain frictional effects in connection with an open dieupset forging operation.

FIG. 3A illustrates the open die upset forging of a cylindricalworkpiece 20 under ideal frictionless conditions. FIG. 3B illustratesthe open die upset forging of an identical cylindrical workpiece 20under high friction conditions. The upper dies 32 press the workpieces20 from their initial height (shown by dashed lines) to a forged heightH. The upsetting force is applied with equal magnitude and in oppositedirection to the workpieces 20 by the upper dies 32 and the lower dies30. The material forming the workpieces 20 is incompressible and,therefore, the volumes of the initial workpieces 20 and the final forgedworkpieces 20 a and 20 b shown in FIGS. 3A and 3B, respectively, areequal. Under the frictionless conditions illustrated in FIG. 3A, theworkpiece 20 deforms uniformly in the axial and radial directions. Thisis indicated by the linear profile 24 a of the forged workpiece 20 a.Under the high friction conditions illustrated in FIG. 3B, the workpiece20 does not deform uniformly in the axial and radial directions. This isindicated by the curved profile 24 b of the forged workpiece 20 b.

In this manner, the forged workpiece 20 b exhibits “barreling” underhigh friction conditions, whereas the forged workpiece 20 a does notexhibit any barreling under frictionless conditions. Barreling and othereffects of non-uniform plastic deformation due to die/workpieceinterface friction during forging are generally undesirable. Forexample, in impression die forging, interface friction may cause theformation of void spaces where deforming material does not fill all thecavities in the die. This may be particularly problematic in net-shapeor near-net-shape forging operations where workpieces are forged withintighter tolerances. High friction conditions can also cause “die-lock”in which the workpiece sticks to the die(s). “Die-lock” may beparticularly undesirable in forging operations involving a contoured diesurface in which a workpiece positioned off-center may die-lock and notproperly deform to take on the contours of the die. As a result, forginglubricants may be employed to reduce interface friction between the diesurfaces and the workpiece surfaces during forging operations.

The following co-owned U.S. patent applications, related to variousdevices and/or methods for decreasing the shear factor for a forgingsystem, are hereby incorporated by reference herein in their respectiveentireties:

U.S. patent application Ser. No. 12/814,591, entitled “LUBRICATIONPROCESSES FOR ENHANCED FORGEABILITY”, published as U.S. PatentApplication Publication No. 2011/0302978; and

U.S. patent application Ser. No. 13/027,327, entitled “LUBRICATIONPROCESSES FOR ENHANCED FORGEABILITY”, published as U.S. PatentApplication Publication No. 2011/0802979.

According to certain non-limiting embodiments, a method of hot workingan alloy ingot or other alloy workpiece according to the presentdisclosure may generally comprise using a multi-layer pad between thealloy ingot or other alloy workpiece and the forging die or otherforging structure to eliminate or reduce surface cracking of the alloyingot or other alloy workpiece. In addition to eliminating or reducingsurface cracking, the multi-layer pad according to the presentdisclosure can also lubricate surfaces of the alloy ingot or other alloyworkpiece during hot working operations. The multi-layer pad cancomprise at least two layers. In various non-limiting embodiments, themulti-layer pad can comprise at least three layers. In at least onenon-limiting embodiments, the multi-layer pad can comprise at least onelubricative layer to reduce friction between the alloy ingot or otheralloy workpiece and the die or other forging structure, for example.Furthermore, in at least one non-limiting embodiment, the multi-layerpad can comprise at least one insulative layer to thermally insulate thealloy ingot or other alloy workpiece from the die or other forgingstructure, for example. In various non-limiting embodiments, themulti-layer pad can comprise a thermally insulative layer positionedintermediate two lubricative layers. In various non-limitingembodiments, the thickness of the insulative layer(s) and thelubricative layer(s) can depend on the material properties of theworkpiece, the temperature gradient between the workpiece and theforging die, and the material(s) of the multi-layer pad, for example. Incertain non-limiting embodiments, the thermally insulative layer(s) canbe sufficiently thick to thermally insulate the workpiece from the die,and the lubricative layer(s) can be sufficiently thick to reducefriction between the workpiece and the die during forging. In variousnon-limiting embodiments, the thermally insulative layer(s) can bethicker than the lubricative layer(s) or vice versa, for example.

Referring now to FIGS. 7 and 8, a non-limiting embodiment of amulti-layer pad 100 that reduces thermal cracking according to thepresent disclosure may generally comprise a plurality of layers 102,104, 106. At least one of the plurality of layers can be a lubricativelayer, for example, which can reduce friction between the alloy ingot orother alloy workpiece and the die or other forging structure. At leastone layer can be a thermally insulative layer, for example, which canthermally insulate the alloy ingot or other alloy workpiece from the dieor other forging structure. In various non-limiting embodiments, alubricative layer can form an outer layer of the multi-layer pad 100,such that the lubricative layer contacts the workpiece and/or the die,for example. In certain non-limiting embodiments, a lubricative layercan form the outer layers of the multi-layer pad 100, such that thelubricative layers contact both the workpiece and the die or otherforging structure, for example. In certain non-limiting embodiments, afirst outer lubricative layer can comprise a workpiece-contactingsurface, for example, and a second outer lubricative layer can comprisea die-contacting surface, for example.

Referring still to FIGS. 7 and 8, in an exemplary embodiment of thepresent disclosure, the layers 102 and 104 can be lubricative layers,which can reduce friction between the workpiece and the die.Furthermore, the layer 106 can be a thermally insulative layer, whichcan thermally insulate the workpiece from the die. In variousnon-limiting embodiments, the insulative layer 106 can be positionedbetween the lubricative layers 102 and 104. In various non-limitingembodiments, the multi-layer pad 100 can include additional layers. Forexample, the multi-layer pad can include a plurality of insulativelayers between the outer lubricative layers. In other non-limitingembodiments, the multi-layer pad can include a plurality of alternatinginsulative and lubricative layers, for example.

In various non-limiting embodiments, the layers of a multi-layer pad canbe secured or held together. For example, referring now to FIGS. 9 and10, staples 118 can secure at least two layers 112, 114, 116 of amulti-layer pad 110 together. In certain non-limiting embodiments, themulti-layer pad 110 can comprise a thermally insulative layer 116sandwiched between two lubricative layers 112, 114 (FIG. 9), forexample. Staples 118 can pierce through the lubricative layers 112 and114 to form a sleeve or pocket, for example. In various non-limitingembodiments, the thermally insulative layer 116 can be slid or otherwisepositioned within the sleeve formed by the joined or stapled outerlubricative layers 112 and 114. In various non-limiting embodiments,rows of staples 118 can extend along the multi-layer pad 110. Forexample, rows of staples 118 can extend along two lateral sides of themulti-layer pad 110. The insulative layer 116 can be slid through anon-stapled side and/or portion of the multi-layer pad 110, for example.In various non-limiting embodiments, at least one staple 118 can piercethrough the inner, insulative layer 116. For example, the insulativelayer 116 can be positioned between the outer, lubricative layers 112,114, and a staple 118 can be applied through the outer and inner layers112, 114, and 116, for example. In such non-limiting embodiments, thestaple 118 can hold the inner, insulative layer 116 relative to theouter, lubricative layers 112 and 114, for example.

Referring now to FIGS. 11 and 12, stitching 128 (FIG. 12) can secure thelayers 122, 124, 126 of a multi-layer pad 120 together. In certainnon-limiting embodiments, the multi-layer pad 120 can comprise athermally insulative layer 126 sandwiched between two lubricative layers122 and 124 for example. In various non-limiting embodiments, thelubricative, outer layers 122 and 124 can be formed from a sheet oflubricative material. The sheet of lubricative material can be foldedalong a line 127 to form a sleeve or pocket, for example, and stitchingcan hold the outer, lubricative layers 122 and 124 together. In certainnon-limiting embodiments, the stitching 128 can extend around at least aportion of the perimeter of the multi-layer pad 110. The stitching canextend along the non-folded edges of the multi-layer pad 120, forexample. In various non-limiting embodiments, the thermally insulativelayer 126 can be slid or otherwise positioned within the sleeve formedby the outer lubricative layers 122 and 124. In certain non-limitingembodiments, at least a portion of the stitching 128 can extend throughthe inner, thermally insulative layer 126. In such non-limitingembodiments, the stitching 128 can hold the inner, thermally insulativelayer 126 relative to the outer, lubricative layers 122 and 124.

In various non-limiting embodiments, a thermally insulative layer forthermally insulating a workpiece from a forging die according to thepresent disclosure can comprise a plurality of ceramic fibers. Accordingto certain non-limiting embodiments, the plurality of the ceramic fibersmay comprise a bundle, a strip or tow, a fabric, and/or a board. Asgenerally used herein the term “fabric” refers to materials that may bewoven, knitted, felted, or fused, to non-woven materials, or tomaterials that otherwise are constructed of fibers. In certainnon-limiting embodiments, the fabric may comprise a binder to hold theplurality of fibers together. In certain non-limiting embodiments, thefabric may comprise one or more of a yarn, a blanket, a mat, a paper, afelt, and the like. In certain non-limiting embodiments, the thermallyinsulative layer can comprise a ceramic fabric such as, for example, aceramic fabric comprising fire clay fibers. For example, the thermallyinsulative layer can comprise KAOWOOL fabric, a material known to thosehaving ordinary skill and which comprises alumina-silica fire clay. Invarious embodiments, the thermally insulative layer can be sufficientlythermally resistant to protect the hot worked workpiece from the coolerdie and/or to prevent or significantly reduce thermal transfer betweenthe two bodies. The thermal resistance of the insulative layer can begreater than the thermal resistance of the lubricative layer of themulti-layer pad, for example. In various non-limiting embodiments, thethermal conductivity of the insulating material can range from 1.45BTU·in/(hr·ft²·° F.) to 2.09 BTU·in/(hr·ft²·° F.) for temperaturesbetween 1500° F. and 2000° F. (816° C. and 1093° C.), for example.

The thicknesses of the insulative layer(s) of a multi-layer pad may varyaccording to the thermal conductivity of the fabric. In certainnon-limiting embodiments, the fabric may have a thickness of 0.5″, 1.0″or 2″, for example. Furthermore, the forms and thicknesses of the one ormore thermally insulative layers of the multi-layer pad may take intoaccount the temperature range over which alloys may be hot worked, e.g.,the temperature at which cracks initiate in the particular alloy that isto be worked. At a given starting temperature for a hot workingoperation, some alloys may be effectively hot worked over a largertemperature range than other alloys because of differences in thetemperature at which cracks initiate in the alloy. For alloys having arelatively small hot working temperature range (i.e., the differencebetween the lowest temperature at which the alloy may be hot worked andthe temperature at which cracks initiate), the thickness of the one ormore thermally insulative layers, and thus, the thickness of themulti-layer pad, may be relatively greater to inhibit or prevent theworkpiece from cooling to a brittle temperature range in which cracksinitiate. Likewise, for alloys having a relatively large hot workingtemperature range, the thickness of the one or more thermally insulativelayers, and thus, the thickness of the multi-layer pad, may berelatively smaller to inhibit or prevent the underlying alloy ingot orother alloy workpiece from cooling to a brittle temperature range inwhich cracks initiate. In various non-limiting embodiments, a pluralityof insulative layers can be stacked and/or layered to achieve athickness sufficient to provide the desired insulative effect.

In various non-limiting embodiments, a lubricative layer for reducingfriction between a workpiece and a forging die according to the presentdisclosure can comprise fiberglass. Fiberglass can comprise a meltingpoint between 1650° F. and 2050° F. (899° C.-1121° C.), for example, andcan comprise SiO₂, Al2O₃, B₂O₃TiO, and/or CaO, for example. In certainnon-limiting embodiments, the lubricative layer can have a lowcoefficient of friction. The lubricative layer can have a coefficient offriction that is less than the coefficient of friction of the workpieceand/or the die, for example. In certain non-limiting embodiments, thelubricative layer can have a coefficient of friction that is less thanthe coefficient of friction of the insulative layer, for example. Invarious embodiments, the coefficient of friction for the lubricativelayer at the forging temperature can range from 0.8 to 1.0, for example.Conversely, the coefficient of friction for metals can range from0.3-0.9, depending on the alloy and temperature.

According to certain non-limiting embodiments, a method of processing analloy ingot or other alloy workpiece to reduce thermal cracking maygenerally comprise initial formation of a workpiece. An alloy ingot orother alloy workpiece described herein may be formed using, for example,conventional metallurgy techniques or powder metallurgy techniques. Forexample, in various non-limiting embodiments, an alloy ingot or otheralloy workpiece may be formed by a combination of vacuum inductionmelting (VIM) and vacuum arc remelting (VAR), known as a VIM-VARoperation. In various other non-limiting embodiments, an alloy workpiecemay be formed by a triple melt technique, in which an electroslagremelting (ESR) operation is performed intermediate a VIM operation anda VAR operation, providing a VIM-ESR-VAR (i.e., triple melt) sequence.In other non-limiting embodiments, an alloy workpiece may be formedusing a powder metallurgy operation involving atomization of moltenalloy and the collection and consolidation of the resultingmetallurgical powders into an alloy workpiece.

In certain non-limiting embodiments, an alloy ingot or other alloyworkpiece may be formed using a spray forming operation. For example,VIM may be used to prepare a base alloy composition from a feedstock. AnESR operation may optionally be used after VIM. Molten alloy may beextracted from a VIM or ESR melt pool and atomized to form moltendroplets. The molten alloy may be extracted from a melt pool using acold wall induction guide (CIG), for example. The molten alloy dropletsmay be deposited into a mold or onto a mandrel or other surface using aspray forming operation to form a solidified alloy workpiece.

In certain non-limiting embodiments, an alloy ingot or other alloyworkpiece may be formed using hot isostatic pressing (HIP). HIPgenerally refers to the isostatic application of a high pressure andhigh temperature gas, such as, for example, argon, to compact andconsolidate powder material into a monolithic preform. The powder may beseparated from the high pressure and high temperature gas by ahermetically sealed container, which functions as a pressure barrierbetween the gas and the powder being compacted and consolidated. Thehermetically sealed container may plastically deform to compact thepowder, and the elevated temperatures may effectively sinter theindividual powder particles together to form a monolithic preform. Auniform compaction pressure may be applied throughout the powder, and ahomogeneous density distribution may be achieved in the preform. Forexample, a near-equiatomic nickel-titanium alloy powder may be loadedinto a metallic container, such as, for example, a steel can, andoutgassed to remove adsorbed moisture and entrapped gas. The containercontaining the near-equiatomic nickel-titanium alloy powder may behermetically sealed under vacuum, such as, for example, by welding. Thesealed container may then be HIP'ed at a temperature and under apressure sufficient to achieve full densification of the nickel-titaniumalloy powder in the container, thereby forming a fully-densifiednear-equiatomic nickel-titanium alloy preform.

After initial workpiece formation, a non-limiting method of processingan alloy ingot or other alloy workpiece to reduce thermal cracking maygenerally comprise heating the workpiece and/or conditioning the surfaceof the workpiece. In certain non-limiting embodiments, an alloyworkpiece may be exposed to high temperatures to homogenize the alloycomposition and microstructure of the workpiece. The high temperaturesmay be above the recrystallization temperature of the alloy but belowthe melting point temperature of the alloy. An alloy workpiece may besurface conditioned, for example, by grinding and/or peeling the surfaceof the workpiece. A workpiece may also be sanded and/or buffed, forexample. Surface conditioning operations may be performed before and/orafter any optional heat treatment steps, such as, for example,homogenization at high temperatures.

According to certain non-limiting embodiments, a method of processing analloy ingot or other alloy workpiece to reduce thermal cracking maygenerally comprise hot working the workpiece. Hot working the workpiecemay comprise applying a force to the workpiece to plastically deform theworkpiece. The force may be applied with, for example, dies and/orrolls. In various non-limiting embodiments, a multi-layer pad accordingto the present disclosure can be positioned between at least a portionof the workpiece and at least a portion of the die(s) or other forgingstructure. For example, referring now to FIGS. 4A and 4B, hot working aworkpiece 40 can comprise upset forging the workpiece 40 in an open die.The open die can comprise a first die portion 50 and a second dieportion 52, for example. In various non-limiting embodiments, theworkpiece 40 can be clamped between the first and second die portions50, 52 such that the workpiece 40 is plastically deformed (FIG. 4B)therebetween. In certain non-limiting embodiments, a multi-layer pad130, 140, can be positioned between at least a portion of the workpiece40 and one of the die portions 50, 52. For example, a first multi-layerpad 140 can be positioned between the first die portion 50 and theworkpiece 40, and a second multi-layer pad 130 can be positioned betweenthe second die portion 52 and the workpiece 40, for example. Themulti-layer pad 130, 140 can be secured to the workpiece 40 and/or tothe die 40, 50. In various embodiments, the multi-layer pad 130, 140 canbe placed on the workpiece 40 and held in position by gravity, forexample. The multi-layer pad 130, 140 may have any suitable width andlength to cover at least a portion of the pre-deformed workpiece 40and/or the deformed workpiece 40 a. The width and length of themulti-layer pad 130, 140 may vary according to the size and/or shape ofthe workpiece 40 and the die 40,50, for example. In various non-limitingembodiments, the multi-layer pads 130, 140 may cover the entireinterface between the workpiece 40 and the die portions 50, 52, forexample. In other non-limiting embodiments, the multi-layer pads 130,140 may only partially cover the interface between the workpiece 40 andthe die portions 50, 52, for example.

Referring now to FIG. 5, hot working a workpiece 80 can comprise upsetforging the workpiece 80 in an impression die 70. The impression die 70can include a punch 72, for example, which can include an impressionand/or a substantially flat punching surface, for example. In variousnon-limiting embodiments, the workpiece 80 can be clamped between theimpression die 70 and the punch 72 such that the workpiece 80 isplastically deformed therebetween. In certain non-limiting embodiments,a multi-layer pad 150, 160, can be positioned between at least a portionof the workpiece 80 and the die 70 and/or the punch 72. For example, afirst multi-layer pad 150 can be positioned between at least a portionof the punch 72 and at least a portion of the workpiece 80, and a secondmulti-layer pad 160 can be positioned between at least a portion of theimpression die 70 and at least a portion of the workpiece 80, forexample. The multi-layer pad 150, 160 can be secured to the workpiece 80and/or to the die 70 and/or the punch 72, for example. In variousembodiments, the multi-layer pad 150, 160 can be placed on the workpiece80 and held in position by gravity, for example. The multi-layer pad150, 160 may have any suitable width and length to cover at least aportion of the workpiece 80. The width and length of the multi-layer pad150, 160 may vary according to the size and/or shape of the workpiece80. In various non-limiting embodiments, the multi-layer pads 150, 160may cover the entire interface between the workpiece 80 and the dieportions 70, 72, for example. In other non-limiting embodiments, themulti-layer pads 150, 160 may only partially cover the interface betweenthe workpiece 80 and the die portions 70, 72, for example.

Referring now to FIGS. 6A and 6B, a fastener 84 formed by the impressiondie upset forging system depicted in FIG. 5, i.e., using multi-layerpads 150, 160 positioned between the workpiece 80 and the impression die70 and between the workpiece 80 and the punch 72, can include a fastenerhead 86. As shown in FIG. 6B, the fastener head 86 formed during theupset forging operation can comprise an outer surface 88 that issubstantially free of surface cracks, for example. Comparatively, thefastener 24 (FIGS. 2A and 2B) formed by the impression die upset forgingoperation depicted in FIGS. 1A-1C, i.e., without the use of amulti-layer pad, includes significantly greater surface cracks on theouter surface 24 thereof.

In certain non-limiting embodiments, hot working the workpiece maycomprise hot working the workpiece at a temperature from 1500° F. to2500° F. Of course, as will be apparent to those having ordinary skill,the temperature range at which hot working may occur for a particularalloy workpiece will be influenced by factors including, for example,the alloy composition and microstructure, the workpiece size and shape,and the particular hot working technique employed. In certainnon-limiting embodiments, hot working the workpiece may comprise aforging operation and/or an extrusion operation. For example, aworkpiece may be upset forged and/or draw forged. In variousnon-limiting embodiments, the method may comprise hot working theworkpiece by forging. In various non-limiting embodiments, the methodmay comprise hot working the workpiece by forging at a temperature from1500° F. to 2500° F. In various non-limiting embodiments, the method maycomprise hot working the workpiece by extruding. In various non-limitingembodiments, the method may comprise hot working the workpiece byextruding at a temperature from 1500° F. to 2500° F.

An upset-and-draw forging operation may comprise one or more sequencesof an upset forging operation and one or more sequences of a drawforging operation. During an upset operation, the end surfaces of analloy ingot or other alloy workpiece may be positioned between forgingdies that apply force to the workpiece and that compress the length ofthe workpiece and increase the cross-section of the workpiece. Amulti-layer pad according to the present disclosure can be positionedbetween the forging dies and the end surfaces of the alloy ingot orother alloy workpiece, for example. During a draw operation, the sidesurfaces (e.g., the circumferential surface of a cylindrical workpiece)may be positioned between forging dies that apply force to the alloyingot or other alloy workpiece that compresses the cross-section of theworkpiece and increases the length of the workpiece. A multi-layer padaccording to the present disclosure can be positioned between theforging dies and the side surfaces of the alloy ingot or other alloyworkpiece, for example.

In various non-limiting embodiments, an alloy ingot or other alloyworkpiece may be subjected to one or more upset-and-draw forgingoperations. For example, in a triple upset-and-draw forging operation, aworkpiece may be first upset forged and then draw forged. The upset anddraw sequence may be repeated two more times, for a total of threesequential upset and draw forging operations. In various non-limitingembodiments, a workpiece may be subjected to one or more extrusionoperations. For example, in an extrusion operation, a cylindricalworkpiece may be forced through a circular die, thereby decreasing thediameter and increasing the length of the workpiece. Other hot workingtechniques will be apparent to those having ordinary skill, and themulti-layer pads and methods according to the present disclosure may beadapted for use with one or more of such other techniques without theneed for undue experimentation.

Although the methods described herein are advantageous for use inconnection with crack sensitive alloys, it will be understood that themethods also are generally applicable to any alloy, including, forexample, alloys characterized by a relatively low ductility at hotworking temperatures, alloys hot worked at temperatures from 1000° F. to2200° F., and alloys not generally prone to cracking. As used herein,the term “alloy” includes conventional alloys, superalloys, and metalsincluding only incidental levels of other elements. As is understood bythose having ordinary skill in the art, superalloys exhibit relativelygood surface stability, corrosion and oxidation resistance, highstrength, and high creep resistance at high temperatures.

Alloy workpieces that may be processed according to the variousembodiments herein may be in any suitable form. In particularnon-limiting embodiments, for example, the alloy workpieces may compriseor be in the form of ingots, billets, bars, plates, tubes, sinteredpre-forms, and the like.

In various non-limiting embodiments, the methods disclosed herein may beused to produce a wrought billet from an alloy ingot in the form of acast, consolidated, or spray formed ingot. The forge conversion orextrusion conversion of an ingot to a billet or other worked article mayproduce a finer grain structure in the article as compared to the formerworkpiece. The methods and processes described herein may improve theyield of forged or extruded products (such as, for example, billets)from workpieces because the multi-layer pad according to the presentdisclosure may reduce the incidence of surface cracking of the workpieceduring the forging and/or extrusion operations. For example, it has beenobserved that a multi-layer pad according to the present disclosureprovided between at least a region of a surface of a workpiece and a diemay more readily tolerate the strain induced by working dies. It alsohas been observed that a multi-layer pad according to the presentdisclosure provided between at least a region of a surface of aworkpiece and a die may also more readily tolerate the temperaturedifferential between the working dies and the workpiece during hotworking. In this manner, it has been observed that surface crackinitiation is prevented or reduced in the underlying workpiece duringworking.

In various non-limiting embodiments, alloy ingots or other alloyworkpieces of various alloys having a multi-layer pad according to thepresent disclosure disposed thereon may be hot worked to form productsthat may be used to fabricate various articles. For example, embodimentsof the processes described herein may be used to form billets from anyof a nickel base alloy, an iron base alloy, a nickel-iron base alloy, atitanium base alloy, a titanium-nickel base alloy, a cobalt base alloy,a nickel base superalloy, and other superalloys. Billets or otherproducts formed from hot worked ingots or other alloy workpieces may beused to fabricate articles including, but not limited to, turbinecomponents, such as, for example, disks and rings for turbine enginesand various land-based turbines. Other articles fabricated from alloyingots or other alloy workpieces processed according to variousnon-limiting embodiments described herein may include, but are notlimited to, valve components, engine components, shafts, and fasteners.

The present disclosure has been written with reference to variousexemplary, illustrative, and non-limiting embodiments. However, it willbe recognized by persons having ordinary skill in the art that varioussubstitutions, modifications, or combinations of any of the disclosedembodiments (or portions thereof) may be made without departing from thescope of the invention as defined solely by the claims. Thus, it iscontemplated and understood that the present disclosure embracesadditional embodiments not expressly set forth herein. Such embodimentsmay be obtained, for example, by combining, modifying, or reorganizingany of the disclosed steps, ingredients, constituents, components,elements, features, aspects, characteristics, limitations, and the like,of the embodiments described herein. Thus, this disclosure is notlimited by the description of the various exemplary, illustrative, andnon-limiting embodiments, but rather solely by the claims. In thismanner, Applicants reserve the right to amend the claims duringprosecution to add features as variously described herein.

What is claimed is:
 1. A multi-layer pad for use during a forgingoperation, wherein the multi-layer pad comprises: a first lubricativelayer; a second lubricative layer; and a first insulative layer, whereinthe first insulative layer is positioned intermediate the first andsecond lubricative layers, and wherein at least one of the first andsecond lubricative layers comprises fiberglass.
 2. The multi-layer padof claim 1, wherein the first lubricative layer further comprises aworkpiece-contacting surface, and wherein the second lubricative layerfurther comprises a die-contacting surface.
 3. The multi-layer pad ofclaim 1, wherein the first insulative layer comprises ceramic fibers. 4.The multi-layer pad of claim 1, wherein the first insulative layercomprises KAOWOOL.
 5. The multi-layer pad of claim 1, wherein acoefficient of friction of the first lubricative layer and a coefficientof friction of the second lubricative layer are less than a coefficientof friction of the first insulative layer.
 6. The multi-layer pad ofclaim 1, wherein a thermal conductivity of the first insulative layer isless than a thermal conductivity of the first lubricative layer and athermal conductivity of the second lubricative layer.
 7. The multi-layerpad of claim 1, further comprising a fastener adapted to fasten at leastthe first and second lubricative layers relative to each other.
 8. Themulti-layer pad of claim 1, wherein the first and second lubricativelayers form a sleeve for the insulative layer.
 9. A method forprocessing an alloy workpiece, comprising: heating the alloy workpieceto a temperature above an ambient temperature; positioning a multi-layerpad between the alloy workpiece and a die, wherein the multi-layer padcomprises a lubrication layer and a thermal resistance layer, whereinthe lubrication layer comprises fiberglass; and hot working the alloyworkpiece.
 10. The method of claim 9, wherein hot working the alloyworkpiece comprises applying a force with the die to the alloy workpieceto deform the alloy workpiece.
 11. The method of claim 10, whereinapplying a force with the die to the alloy workpiece to deform the alloyworkpiece comprises upset forging the alloy workpiece.
 12. The method ofclaim 9, further comprising positioning a plurality of multi-layer padsbetween the alloy workpiece and at least one die.
 13. The method ofclaim 9, further comprising pre-forming the alloy workpiece.
 14. Themethod of claim 9, further comprising fabricating an article from thehot worked alloy workpiece, wherein the article is selected from thegroup consisting of a jet engine component, a land based turbinecomponent, a valve, an engine component, a shaft, and a fastener. 15.The method of claim 9, wherein heating the alloy workpiece to atemperature above the ambient temperature comprises heating the alloyworkpiece above a recrystallization temperature of the alloy and belowthe melting point temperature of the alloy.
 16. The method of claim 9,wherein the alloy workpiece comprises one of an ingot, a billet, a bar,a plate, a tube, and a sintered pre-form.
 17. The method of claim 9,wherein the alloy workpiece comprises a crack sensitive alloy.
 18. Themethod of claim 9, wherein the alloy workpiece comprises a materialselected from the group consisting of Alloy 718 (UNS No. N07718), Alloy720 (UNS No. N07720), Rene 41 alloy (UNS No. N07041), Rene 65 alloy,Rene 88 alloy, WASPALOY® alloy (UNS No. N07001), and INCONEL® 100 alloy.19. The method of claim 9, wherein a coefficient of friction of thelubrication layer is less than a coefficient of friction of the thermalresistance layer.
 20. The method of claim 9, wherein the thermalresistance layer comprises KAOWOOL.
 21. The method of claim 20, whereina thermal resistance of the thermal resistance layer is greater than athermal resistance of the lubrication layer.
 22. An alloy workpieceprocessed by the method of claim
 9. 23. A hot worked article formed froman alloy workpiece by a process comprising the method of claim 9.